55510-08-2Relevant articles and documents
Transformation of Methylene Acetals to Bromoformates with a Combination of Trimethyl(phenylthio)silane and N-Bromosuccinimide
Maegawa, Tomohiro,Nogata, Misa,Hirose, Yuuka,Ohgami, Shun,Nakamura, Akira,Miki, Yasuyoshi,Fujioka, Hiromichi
, p. 7608 - 7613 (2017/07/26)
A novel transformation reaction of methylene acetals, using a combination of trimethyl(phenylthio)silane (PhSTMS) and N-bromosuccinimide (NBS) under mild reaction conditions, is described. Various methylene acetals were converted to their corresponding br
Solvation and steric effects on electrophilic reactivity of ethylenic compounds. 2. Kinetic criteria for nucleophilic assistance and return in bromination
Ruasse, Marie-Fran?ois,Motallebi, Shahrokh,Galland, Bernard
, p. 3440 - 3446 (2007/10/02)
Three kinetic criteria, mBr, R (kaqEtOH/kAcOH)Y, and KSIE (kinetic solvent isotope effect), are used to estimate the magnitude of the electrophilic and nucleophilic involvement of protic solvents and the occurre