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([(1Z)-1,3-Diphenyl-1-butenyl]oxy)(trimethyl)silane, also known as 1,3-diphenylprop-1-enyl(trimethyl)silane, is an organosilane compound with the molecular formula C22H26OSi. It is a versatile reagent in organic synthesis and polymer chemistry, characterized by a trimethylsilyl group attached to a phenyl group and a 1,3-diphenyl-1-butenyl group. ([(1Z)-1,3-Diphenyl-1-butenyl]oxy)(trimethyl)silane is instrumental in the creation of silicon-containing polymers and serves as a precursor in the production of various silicone-based materials. Additionally, it is recognized for its role in the preparation of functionalized silanes and in the protection of hydroxyl groups in organic synthesis.

55543-94-7

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55543-94-7 Usage

Uses

Used in Organic Synthesis:
([(1Z)-1,3-Diphenyl-1-butenyl]oxy)(trimethyl)silane is used as a reagent in organic synthesis for its ability to facilitate various chemical reactions, enhancing the efficiency and selectivity of the processes involved.
Used in Polymer Chemistry:
As a coupling agent in polymer chemistry, this organosilane compound is utilized to connect different polymer chains or monomers, contributing to the formation of complex polymer structures with desired properties.
Used in the Creation of Silicon-Containing Polymers:
([(1Z)-1,3-Diphenyl-1-butenyl]oxy)(trimethyl)silane is used as a key component in the synthesis of silicon-containing polymers, which are valued for their unique properties such as thermal stability, oxidative resistance, and flexibility.
Used in the Production of Silicone-Based Materials:
([(1Z)-1,3-Diphenyl-1-butenyl]oxy)(trimethyl)silane serves as a precursor in the production of various silicone-based materials, which are widely used in industries such as automotive, aerospace, construction, and electronics due to their exceptional performance characteristics.
Used in the Preparation of Functionalized Silanes:
[((1Z)-1,3-Diphenyl-1-butenyl]oxy)(trimethyl)silane is employed in the preparation of functionalized silanes, which are important intermediates in the synthesis of a range of silicon-containing compounds with specific applications in various fields.
Used in the Protection of Hydroxyl Groups in Organic Synthesis:
In organic synthesis, ([(1Z)-1,3-Diphenyl-1-butenyl]oxy)(trimethyl)silane is used for the protection of hydroxyl groups, a common strategy to prevent unwanted side reactions and to control the reactivity of functional groups during complex chemical transformations.

Check Digit Verification of cas no

The CAS Registry Mumber 55543-94-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,5,5,4 and 3 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 55543-94:
(7*5)+(6*5)+(5*5)+(4*4)+(3*3)+(2*9)+(1*4)=137
137 % 10 = 7
So 55543-94-7 is a valid CAS Registry Number.

55543-94-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,3-diphenylbut-1-enoxy(trimethyl)silane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:55543-94-7 SDS

55543-94-7Relevant academic research and scientific papers

The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent to a Stereogenic Centre: Diastereoselective Alkylation and Protonation of Open-chain Enolates having a Stereogenic Centre at the β Position

Fleming, Ian,Lewis, Jeremy J.

, p. 3257 - 3266 (2007/10/02)

Methylation of the enolates 7, 24, 28 and 33 and protonation of the enolates 10, 27, 31 and 36 are diastereoselective in conformity to a general rule, summarised in the drawing 1, governing the stereochemistry of electrophilic attack on a double bond adjacent to a stereogenic centre.The sense of the selectivity is, with one exception, opposite to that of the corresponding nucleophilic attack on a carbonyl group adjacent to a stereogenic centre, which, with the same exception, follows Cram's and the Felkin-Anh rule, summarised in the drawing 2.The exception is probably the reduction 40 -> 38 + 39, with 39 as the major product.This result is inconsistent with Cram's and the Felkin-Anh rule if the isopropyl group is counted as 'larger' than the phenyl group, whereas the Grignard reaction 37 -> 38 + 39, where 39 is again the major product, and the corresponding electrophilic reactions 33 -> 34 + 35, with 34 as the major product, and 36 -> 34 + 35, with 35 as the major product, are all consistent with isopropyl being effectively larger than phenyl.

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