556777-01-6Relevant academic research and scientific papers
Uniting Anion Relay Chemistry with Pd-mediated Cross Coupling: Design, synthesis and evaluation of bifunctional aryl and vinyl silane linchpins
Smith III, Amos B.,Kim, Won-Suk,Tong, Rongbiao
supporting information; experimental part, p. 588 - 591 (2010/05/18)
[Chemical equation presented] Union of type II Anion Relay Chemistry (ARC) with Pd-induced Cross Coupling Reactions (CCR) has been achieved, In conjunction with the design, synthesis, and evaluation of a new class of bifunctional linchpins, comprising a series of vinyl silanes bearing - or γ-electrophilic sites. The synthetic tactic permits both alkylation and Pd-mediated CCR of the anions derived via 1,4-silyl C(sp2) -O Brook Rearrangements.
Ruthenium-catalyzed vinylsilane synthesis and cross-coupling as a selective approach to alkenes: benzyldimethylsilyl as a robust vinylmetal functionality.
Trost, Barry M,Machacek, Michelle R,Ball, Zachary T
, p. 1895 - 1898 (2007/10/03)
[reaction: see text] Ruthenium-catalyzed alkyne hydrosilylation or silyl-alkyne Alder ene reactions provide entry into benzyldimethylsilyl (BDMS)-substituted alkenes. The BDMS-vinylsilanes are further elaborated through mild palladium-catalyzed cross coup
