557087-94-2

Upstream product

• 557088-28-5 methyl (4R)-2,3,6-tri-O-benzyl-4-deoxy-4-(2-ethanal)-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 138607-79-1 (2S,3R,4S,4aS,8aS)-3,4-Bis-benzyloxy-2-methoxy-hexahydro-pyrano[3,4-b]pyran-6-one 
• 138607-78-0 3,4-dibenzyloxy-2-methoxy-3,4,8,8a-tetrahydro-2H-pyrano[3,4-b]pyran-6-one 

Downstream Products

• 557088-06-9 ((2S,3S,4S,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yl)-acetic acid (1R,2S,3R)-2,3-bis-benzyloxy-1-benzyloxymethyl-pent-4-enyl ester 
• 557088-07-0 (2S,3R,4S,5S,6S)-3,4-Bis-benzyloxy-6-benzyloxymethyl-5-[2-((1R,2S,3R)-2,3-bis-benzyloxy-1-benzyloxymethyl-pent-4-enyloxy)-allyl]-2-methoxy-tetrahydro-pyran 

Relevant academic research and scientific papers

Synthesis and partial biological evaluation of a small library of differentially-linked β-C-disaccharides

The synthesis of a small library of differentially-linked β-C-disaccharides has been carried out through the use of a radical allylation-RCM strategy. Acids 6 were prepared by Keck allylation of a suitable carbohydrate-based radical precursor, followed by

Preferred Conformation of C-Glycosides. 8. Synthesis of 1,4-Linked Carbon Disaccharides

Three general synthetic routes to 1,4-linked carbon disaccharides (e.g., 3, 4, 15-17, 21-23, 44, and 45) are presented.Control of the stereochemistry at C.1', C.2', C.5'and C.4, the incorporation of deuterium labels at the C.α position, and structural mod