55847-15-9Relevant academic research and scientific papers
B(C6F5)3-Catalyzed C-H Alkylation of N-Alkylamines Using Silicon Enolates without External Oxidant
Chan, Jessica Z.,Chang, Yejin,Wasa, Masayuki
supporting information, p. 984 - 988 (2019/02/14)
An efficient method for the coupling of N-alkylamines with silicon enolates to generate β-amino carbonyl compounds is disclosed. These reactions proceed by activation of α-amino C-H bonds by B(C6F5)3, which likely generate
Di- And trifluorobenzenes in reactions with Me2em (E = P, N; M = SiMe3, SnMe3, Li) reagents: Evidence for a concerted mechanism of aromatic nucleophilic substitution
Goryunov, Leonid I.,Grobe, Joseph,Le Van, Due,Shteingarts, Vitalij D.,Mews, Ruediger,Lork, Enno,Wuerthwein, Ernst-Ulrich
experimental part, p. 1111 - 1123 (2010/04/27)
Dimethyl(trimethylsilyl)phosphane (Me3SiPMe2) has been successfully used for the substitution of fluorine variously in 1,3- (1) or 1,2-difluorobenzene (2) or in 1,3,5- (3) or 1,2,3trifluorobenzene (4) by the Me2P group at
