55881-64-6Relevant articles and documents
Substituent-controlled annuloselectivity and stereoselectivity in the sulfa-Staudinger cycloadditions
Yang, Zhanhui,Chen, Ning,Xu, Jiaxi
, p. 3611 - 3620 (2015/04/22)
In the sulfa-Staudinger cycloadditions of imines and sulfonyl chlorides, the annuloselectivity is mainly controlled by the electronic effect of the α-substituents of sulfonyl chlorides and the nucleophilicity of imines. Sulfonyl chlorides with weakly elec
A simple and one-pot synthesis of β-sultams by using the vilsmeier reagent
Zarei, Maaroof,Jarrahpour, Aliasghar
, p. 438 - 441 (2013/06/05)
Mild and efficient one-pot synthesis of β-sultams with the Vilsmeier reagent proceeded in good to excellent yield. [2 + 2] Cycloaddition of imines with sulfenes (prepared in situ) afforded the corresponding cis-β-sultams. Optimization of solvents, molar ratio of reagents,and temperature was performed. Toxic and corrosive compounds have been avoided in this novel method.
Synthesis and Configuration of 4-Alkyl-2-methyl-3,4-diphenyl-1,2-thiazetidine 1,1-Dioxide
Grunder, Evelyne,Leclerc, Gerard,Ehrhardt, Jean-Daniel
, p. 1781 - 1785 (2007/10/02)
4-Alkyl-2-methyl-3,4-diphenyl-1,2-thiazetidine 1,1-dioxide 5, 6 and 7 were obtained from 2-methyl-3,4-diphenyl-1,2-thiazetidine 1,1-dioxide 1 by reaction of its anion 4 with alkyl halides. cis- and trans-Configuration of 4-alkylated products were determined by 1H-nmr and NOE difference spectroscopy studies.