55882-01-4Relevant academic research and scientific papers
Simultaneous scission of C-S and S-S bonds of bis(trifluoromethyl)trisulfide by Grignard reagents
Munavalli, Shekar,Rossman, David I.,Rohrbaugh, Dennis K.,Ferguson, C. Parker,Szafraniec, Leonard J.
, p. 91 - 99 (2007/10/02)
Trifluoromethyl mono-, di- and tri-sulfides, and alkyl sulfides and disulfides, as well as dimerized products, are formed as a result of the simultaneous cleavage of the C-S and S-S bonds of bis(trifluoromethyl)trisulfide by Grignard reagents at -78 deg C.The formation of various products has been rationalized on the basis of the involvement of free radicals.
