560095-81-0

Basic information

• Product Name: Phosphoric triamide, pentamethyl[3-(methylthio)-1-phenyl-1-propenyl]-
• CAS NO: 560095-81-0
• Molecular Formula: C15H26N3OPS
• Molecular Weight: 327.431
• Mol File: 560095-81-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphoric triamide, pentamethyl[3-(methylthio)-1-phenyl-1-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric triamide, pentamethyl[3-(methylthio)-1-phenyl-1-propenyl]-(560095-81-0)
• EPA Substance Registry System: Phosphoric triamide, pentamethyl[3-(methylthio)-1-phenyl-1-propenyl]-(560095-81-0)

Safety Data

• Hazardous Substances Data: 560095-81-0(Hazardous Substances Data)

Upstream product

• 624-92-0 Dimethyldisulphide 
• 560095-49-0 (1-phenyl-2-propen-1-yl)pentamethyl phosphoric triamide 
• 560095-46-7 C₁₃H₂₂N₃OP 
• 560095-43-4 (1-phenyl-2-propen-1-yl)amidophosphoric dichloride 
• 4393-21-9 1-(phenyl)allylamine 

Downstream Products

• 29777-54-6 3-methylsulfanyl-1-phenyl-1-propanone 

Relevant articles and documents

New ketone homoenolate anion equivalents derived from (alkenyl)pentamethyl phosphoric triamides

Lithiated ambident anions derived from (1-alkyl-2-propenyl)- or (1-phenyl-2-propenyl)-pentamethyl phosphoric triamides undergo regioselectively γ-reaction with various alkylating reagents and isobutyraldehyde. Further hydrolysis of adducts releases the ketone under acid conditions. Number of synthetic applications clearly show the ketone homoenolate behaviour of these new carbanions.