56060-53-8Relevant academic research and scientific papers
Copper-catalyzed oxidative desulfurization-promoted intramolecular cyclization of thioamides using molecular oxygen as an oxidant: An efficient route to five- To seven-membered nitrogen-containing heterocycles
Shibahara, Fumitoshi,Yoshida, Atsunori,Murai, Toshiaki
, p. 646 - 647 (2008/12/21)
Copper-catalyzed oxidative desulfurization-promoted intramolecular cyclization reactions of thioamides take place under neutral and mild conditions by using molecular oxygen as an oxidant. The process yields a wide variety of nitrogen-containing heterocyc
N-thioacyl 1,3-amino alcohols: Synthesis via ring-opening of oxiranes with thioamide dianions and applications as key intermediates leading to stereochemically defined 5,6-dihydro-4H-1,3-oxazines and 1,3-amino alcohols
Murai, Toshiaki,Sano, Hiroaki,Kawai, Hiroyasu,Aso, Hideo,Shibahara, Fumitoshi
, p. 8148 - 8153 (2007/10/03)
N-Thioacyl 1,3-amino alcohols were synthesized via the ring-opening of oxiranes with thioamide dianions generated from N-benzyl thioamides and BuLi in a highly regio- and stereoselective manner. The diastereomers of N-thioacyl 1,3-amino alcohols were read
