56080-53-6Relevant academic research and scientific papers
Synthesis of 2-methylidene-1-silacyclohexanes by intramolecular hydrosilylation
Díez-González, Silvia,Blanco, Luis
, p. 2033 - 2040 (2008/09/19)
The preparation of various (hex-5-ynyl)silanes was achieved following two different synthetic approaches from readily available materials such as 4-bromobutene, 6-iodohexyne and chlorosilanes. Different reaction conditions for intramolecular hydrosilylation were tested to prepare the corresponding 2-methylidene-1-silacyclohexanes. Notably, the use of Speier's catalyst allowed the regioselective formation of the desired products in moderate yields.
