56152-84-2Relevant academic research and scientific papers
A new protocol for nickel-catalysed regio- and stereoselective hydrocyanation of allenes
Arai, Shigeru,Hori, Hiroto,Amako, Yuka,Nishida, Atsushi
supporting information, p. 7493 - 7496 (2015/05/04)
Regio- and stereoselective hydrocyanation under nickel catalysis is described. This report shows that allenyl C-C double bonds are discriminated and converted to the corresponding carbonitriles as a single product. The key functionalities for achieving high regio- and stereocontrol are aryl and cyclopropyl groups in the substrates. This journal is
Cationic carbenoid rearrangement of 2-phenyl substituted gem-dihalogenospiropentanes
Sedenkova, Kseniya N.,Averina, Elena B.,Grishin, Yuri K.,Rybakov, Victor B.,Kuznetzova, Tamara S.,Zefirov, Nikolay S.
experimental part, p. 4145 - 4150 (2010/09/10)
The series of 2-phenyl- and 2,2-diphenyl gem-dihalogenospiropentanes were employed as model compounds to study the carbenoid rearrangement with the use of methyllithium. The scope and limitations of this skeletal rearrangement are outlined and its mechani
SPIROPENTANES. III. SYNTHESIS OF gem-DIHALOGENOSPIROPENTANES
Formanovskii, A. A.,Kozotsyna, N. Yu.,Bolesov, I. G.
, p. 71 - 76 (2007/10/02)
A series of the simplest alkyl- and phenyl-gem-dihalogenospiropentanes were synthesized by the condensation of alkyl- and arylmethylenecyclopropanes with dichloro- and dibromocarbenes.The introduction of substituents into the three-membered ring leads to
