56152-85-3Relevant academic research and scientific papers
Cationic carbenoid rearrangement of 2-phenyl substituted gem-dihalogenospiropentanes
Sedenkova, Kseniya N.,Averina, Elena B.,Grishin, Yuri K.,Rybakov, Victor B.,Kuznetzova, Tamara S.,Zefirov, Nikolay S.
experimental part, p. 4145 - 4150 (2010/09/10)
The series of 2-phenyl- and 2,2-diphenyl gem-dihalogenospiropentanes were employed as model compounds to study the carbenoid rearrangement with the use of methyllithium. The scope and limitations of this skeletal rearrangement are outlined and its mechani
