56161-54-7

Basic information

• Product Name: 1,3-Dioxolane, 2-methyl-2-[2-(phenylsulfonyl)ethyl]-
• Synonyms: 4-phenylsulfonyl-2-butanone ethylene acetal
• CAS NO: 56161-54-7
• Molecular Formula: C12H16O4S
• Molecular Weight: 256.323
• Mol File: 56161-54-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane, 2-methyl-2-[2-(phenylsulfonyl)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 2-methyl-2-[2-(phenylsulfonyl)ethyl]-(56161-54-7)
• EPA Substance Registry System: 1,3-Dioxolane, 2-methyl-2-[2-(phenylsulfonyl)ethyl]-(56161-54-7)

Safety Data

• Hazardous Substances Data: 56161-54-7(Hazardous Substances Data)

Upstream product

• 497-26-7 2-methyl-1,3-dioxolane 
• 5535-48-8 PVS 
• 38798-68-4 phenyl β-bromoethyl sulphone 
• 24731-39-3 4-(phenylsulfonyl)butan-2-one 
• 107-21-1 ethylene glycol 

Downstream Products

• 2235-83-8 5-phenyl-2-pentanone 
• 5609-09-6 3-hepten-2-one 
• 57398-49-9 4-Benzenesulfonyl-heptan-2-one 
• 172534-55-3 4-dimethylphenylsilyl-4-phenylsulfonylbutan-2-one 
• 172534-54-2 4-tert-butyldimethylsilyl-4-phenylsulfonylbutan-2-one 
• 83802-98-6 4-phenylsulfonyl-4-trimethylsilylbutan-2-one 
• 213828-18-3 2-[(R)-2-Benzenesulfonyl-4-((1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-ethoxy-3a,5a-dimethyl-hexadecahydro-cyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)-pentyl]-2-methyl-[1,3]dioxolane 
• 172534-53-1 4-dimethylphenylsilyl-4-phenylsulfonylbutan-2-one ethylene acetal 
• 172534-52-0 4-tert-butyldimethylsilyl-4-phenylsulfonylbutan-2-one ethylene acetal 
• 83802-93-1 4-phenylsulfonyl-4-trimethylsilylbutan-2-one ethylene acetal 
• 117120-82-8 (4R,5R)-4-Ethyl-2,2-dimethyl-5-<3-(2-methyl-1,3-dioxolan-2-yl)-2-(phenylsulfonyl)propyl>-1,3-dioxolan 
• 117120-82-8 (4S,5S)-4-Ethyl-2,2-dimethyl-5-<3-(2-methyl-1,3-dioxolan-2-yl)-2-(phenylsulfonyl)propyl>-1,3-dioxolan 
• 121405-06-9 (-)-(4S,5S)-2,2-Dimethyl-4-<2-phenylsulfonyl-3-(2-methyl-1,3-dioxolan-2-yl)propyl>-5-vinyl-1,3-dioxolane 
• 121405-06-9 (+/-)-2,2-Dimethyl-4-<2-phenylsulfonyl-3-(2-methyl-1,3-dioxolan-2-yl)propyl>-5-vinyl-1,3-dioxolane 

Relevant articles and documents

Metal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2

Presented is a light-promoted C-C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This transformation proceeds in neat conditions through an auto-oxidation mechanism which is maintained through the leaching of trace amounts of O2 as sole green oxidant. This journal is

Practical β-masked formylation and acetylation of electron-deficient olefins utilizing tetra(n-butyl)ammonium peroxydisulfate

Various electron-deficient olefins reacted readily with 1,3-dioxolane or 2-methyl-1,3-dioxlane in the presence of TBAP to afford the corresponding 1,3-dioxolanylated or 2-methyl-1,3-dioxolanylated products in a complete regioselective manner in good to ex

Synthesis and reactivity of iron carbonyl complexes of β-silyl substituted α,β-unsaturated ketones

β-Silyl α,β-unsaturated ketones, R3SiCH=CHC(O)Me (R3Si = Me3Si, ButMe2Si, PhMe2Si), react with at 35 deg C in diethyl ether to give tetracarbonyliron(0) complexes and at 55 deg C in toluene to give tricarbonyliron(0) complexes.Tricarbonyliron(0) and tricarbonyltMe2SiCH=CHC(O)Me>iron(0) react with methyllithium under a nitrogen atmosphere to give hexane-2,5-dione and 3-(tert-butyldimethylsilyl)hexane-2,5-dione, respectively, and with methyllithium under a carbon monoxide atmosphere to give the vinylketene complexes tricarbonyl(3-methyl-5-trimethylsilyl-1-oxa-1,2,4-triene)iron(0) and tricarbonyl(5-tert-butyldimethylsilyl-3-methyl-1-oxapenta-1,2,4-triene)iron(0) respectively.