56263-58-2Relevant academic research and scientific papers
Evidence for the transition between concerted and stepwise heterogeneous electron transfer-bond fragmentation mechanisms
Antonello, Sabrina,Maran, Flavio
, p. 12595 - 12600 (1997)
The electrochemical reduction of tert-butyl p-cyanoperbenzoate in DMF leads to the cleavage of the oxygen-oxygen bond. A subsequent reaction yielding tert-butyl p-cyanobenzoate could be avoided by the addition of a mild acid, with the result that the main
Temperature-controlled solvent-free selective synthesis of tert-butyl peresters or acids from benzyl cyanides in the presence of the TBHP/Cu(OAc)2 system
Hashemi,Saberi,Poorsadeghi,Niknam
, p. 7619 - 7622 (2017/02/05)
Solvent-free room temperature synthesis of tert-butyl peresters was achieved via copper-catalyzed oxidative-coupling of benzyl cyanides with tert-butyl hydroperoxide in short reaction times. Various derivatives of tert-butyl peresters were synthesized by this pathway in good to excellent yields. Further investigation revealed that the above-mentioned protocol is effective for the synthesis of benzoic acid derivatives when the reaction is conducted at 80?°C, under the same reaction conditions.
