562835-16-9

Basic information

• Product Name: Ethanol, 2-[(3R,4R,5R)-3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-4-(phenylmethoxy )-1,6-dioxaspiro[4.5]dec-2-ylidene]-, (2E)-
• CAS NO: 562835-16-9
• Molecular Formula: C33H40O5Si
• Molecular Weight: 544.763
• Mol File: 562835-16-9.mol

Chemical Properties

• CAS DataBase Reference: Ethanol, 2-[(3R,4R,5R)-3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-4-(phenylmethoxy )-1,6-dioxaspiro[4.5]dec-2-ylidene]-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanol, 2-[(3R,4R,5R)-3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-4-(phenylmethoxy )-1,6-dioxaspiro[4.5]dec-2-ylidene]-, (2E)-(562835-16-9)
• EPA Substance Registry System: Ethanol, 2-[(3R,4R,5R)-3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-4-(phenylmethoxy )-1,6-dioxaspiro[4.5]dec-2-ylidene]-, (2E)-(562835-16-9)

Safety Data

• Hazardous Substances Data: 562835-16-9(Hazardous Substances Data)

Upstream product

• 562835-12-5 (3S,4R)-4-benzyloxy-9-(tert-butyldimethylsiloxy)-3-(tert-butyldiphenylsiloxy)-1-nonyn-5-one 
• 1027289-83-3 (3S,4R)-4-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxy)-9-hydroxy-non-1-yn-5-one 
• 562835-13-6 (2E,3R,4R,5R)-4-benzyloxy-3-(tert-butyldiphenylsiloxy)-2-methoxycarbonylmethylidene-1,6-dioxaspiro[4.5]decane 
• 92511-12-1 1-{[dimethyl(1,1-dimethylethyl)silyl]oxy}-4-iodobutane 

Downstream Products

• 562835-17-0 (2E,3R,4R,5R)-3-(tert-butyldiphenylsiloxy)-2-(2-hydroxyethylidene)-1,6-dioxaspiro[4.5]decan-4-ol 
• 562835-19-2 (2E,3R,4R,5R)-4-benzyloxy-2-propynylidene-1,6-dioxaspiro[4.5]decan-3-ol 
• 562835-21-6 (2E,3R,4R,5R)-4-benzoyloxy-2-propynylidene-1,6-dioxaspiro[4.5]decan-3-ol 
• 562835-23-8 (2E,3R,4R,5R)-4-benzoyloxy-2-(2,4-hexadiynylidene)-1,6-dioxaspiro[4.5]decan-3-ol 
• 562835-20-5 (2E,3R,4R,5R)-3-(tert-butyldiphenylsiloxy)-2-propynylidene-1,6-dioxaspiro[4.5]decan-4-ol 
• 562835-18-1 (2E,3R,4R,5R)-4-benzyloxy-3-(tert-butyldiphenylsiloxy)-2-propynylidene-1,6-dioxaspiro[4.5]decane 

Relevant articles and documents

First total synthesis of (-)-AL-2

(Matrix presented) Treatment of the 3,4-dioxygenated-9-hydroxy-1-nonyn-5-one derivative, derived from diethyl L-tartrate, with a palladium catalyst in methanol under a CO atmosphere effected an intramolecular acetalization and a stereoselective constructi

Total syntheses of naturally occurring diacetylenic spiroacetal enol ethers

A highly stereoselective method for constructing a (2E)-methoxymethylidene- 1,6-dioxaspiro[4.5]-decane skeleton has been developed on the basis of the palladium(II)-catalyzed ring-closing reaction of the 3,4-dioxygenated-9-hydroxy- 1-nonyn-5-one derivativ