5633-78-3

Basic information

• Product Name: 2-Hexylthiirane
• Synonyms: 1,2-Epithiooctane;2-Hexylthiirane;Hexylthiirane
• CAS NO: 5633-78-3
• Molecular Formula: C₈H₁₆S
• Molecular Weight: 370.4255
• Mol File: 5633-78-3.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 555.9°Cat760mmHg
• Flash Point: 290°C
• Appearance: /
• Density: 1.37g/cm³
• Vapor Pressure: 2.14E-12mmHg at 25°C
• Refractive Index: 1.664
• CAS DataBase Reference: 2-Hexylthiirane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexylthiirane(5633-78-3)
• EPA Substance Registry System: 2-Hexylthiirane(5633-78-3)

Safety Data

• Hazardous Substances Data: 5633-78-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H18N4O3S/c1-12-3-7-15(8-4-12)22-18(23)17(13(2)21-22)11-20-14-5-9-16(10-6-14)26(19,24)25/h3-11,20H,1-2H3,(H2,19,24,25)/b17-11-

Upstream product

• 75-15-0 carbon disulfide 
• 2984-50-1 1,2-Epoxyoctane 
• 17356-08-0 thiourea 
• 96738-42-0 5-hexyl-1,3-oxathiolane-2-thione 
• 83048-90-2 2-iodo-1-thiocyanato-octane 

Downstream Products

• 3001-66-9 octane-2-thiol 
• 69036-39-1 1-octen-1-yl phenyl sulfide 
• 867018-45-9 1-N,N-dibenzylamino-2-octylmercaptan 
• 867018-51-7 1-N,N-dibenzylaminooctane-2-sulfonic acid 

Relevant articles and documents

Copper-Catalyzed Oxyalkynylation of C-S Bonds in Thiiranes and Thiethanes with Hypervalent Iodine Reagents

We report the oxyalkynylation of thiiranes and thietanes using ethynylbenziodoxolone reagents (EBXs) to readily access functionalized building blocks bearing an alkynyl, a benzoate, and an iodide group. The reaction proceeds with high atom efficiency most

A green method for solvent-free conversion of epoxides to thiiranes using NH4SCN in the presence of NiFe2O4 and MgFe2O4 magnetic nanocatalysts

Nickel and magnesium ferrite magnetic nanoparticles were fabricated and applied as efficient and reusable catalysts in the solvent-free conversion of various epoxides to the corresponding thiiranes with ammonium thiocyanate under oil bath (60°C) conditions. NiFe2O4 and MgFe2O4 nanoparticles can catalyze the reactions at short times in high to excellent yields. The catalysts can also be recovered easily using an external magnetic field and be reused four times without any significant loss of activity.

Synthesis of 3-acyl-5,6-dihydro-1,4-oxathiines through ring expansion of thiiranes

Synthesis of 3-acyl-5,6-dihydro-1,4-oxathiines has been achieved via reactions of thiiranes and α-diazo-β-1,3-dicarbonyl compounds under microwave and copper sulfate-assisted conditions. The current method provides a direct and simple strategy in efficient preparation of 3-acyl-1,4-oxathiines from readily available thiiranes and trans-3-acyl-5,6-dihydro-1,4-oxathiines as stereospecific products for 1,2-disubstituted cis-thiiranes. The reaction mechanism was also proposed.