5637-83-2Relevant academic research and scientific papers
Improving stability of the metal-free primary energetic cyanuric triazide (CTA) through cocrystallization
Du Bois, Derek R.,Foroughi, Leila M.,Matzger, Adam J.,Wiscons, Ren A.
, p. 2111 - 2114 (2020)
Cyanuric triazide (CTA) and benzotrifuroxan (BTF) form a metal-free primary energetic cocrystal with suppressed volatility and improved thermal properties relative to CTA. Though electrostatic potential maps of the most stable conformations do not predict favorable interactions, a higher energy conformer has appropriate electrostatics and is selected by BTF in the cocrystal.
Organocatalytic Enamine–Azide Addition Reaction in the Synthesis of 1,4,5-Trisubstituted 1,2,3-Triazoles
Sokolnikova,Proidakov,Kizhnyaev
, p. 376 - 382 (2021/04/13)
Abstract: A high efficiency of diethanolamine as organocatalyst in the cycloaddition of organic (including heterocyclic) mono-, di-, and triazides to active methylene compounds has been demonstrated. As a result, a number of functionally substituted bi- a
Synthesis of azidopropargylamino-substituted 1,3,5-triazines – novel monomers for the production of energetic polymers
Shastin, Aleksey V.,Petrov, Artem O.,Malkov, Georgiy V.,Gavrishova, Tatiana N.
, p. 866 - 870 (2021/09/08)
[Figure not available: see fulltext.] Efficient methods for the synthesis of novel azidopropargylamino-substituted 1,3,5-triazines were developed. 4,6-Diazido-N-(prop-2-yn-1-yl)-1,3,5-triazin-2-amine was obtained by the method of sequential nucleophilic substitution of chlorine atoms in cyanuric chloride by amino and azido groups or by the method of selective substitution of the azido group in triazidotriazine with propargylamine. 6-Azido-N2,N4-dimethyl-N2,N4-di(prop-2-yn-1-yl)-1,3,5-triazine-2,4-diamine was obtained by nitrosation of the corresponding 6-hydrazinyl-N2,N4-dimethyl-N2,N4-di(prop-2-yn-1-yl)-1,3,5-triazine-2,4-diamine. Monomers with a lower melting point were obtained by N-methylation of azidopropargylamino-substituted 1,3,5-triazines.
Synthesis and unique photoluminescence properties of nitrogen-rich quantum dots and their applications
Chen, Xiuxian,Jin, Qingqing,Wu, Lizhu,Tung, ChenHo,Tang, Xinjing
supporting information, p. 12542 - 12547 (2015/04/16)
Nitrogen-rich quantum dots (N-dots) were serendipitously synthesized in methanol or aqueous solution at a reaction temperature as low as 50 °C. These N-dots have a small size (less than 10 nm) and contain a high percentage of the element nitrogen, and are thus a new member of quantumdot family. These N-dots show unique and distinct photoluminescence properties with an increasing percentage of nitrogen compared to the neighboring carbon dots. The photoluminescence behavior was adjusted from blue to green simply through variation of the reaction temperature. Furthermore, the detailed mechanism of N-dot formation was also proposed with the trapped intermediate. These N-dots have also shown promising applications as fluorescent ink and biocompatible staining in C. elegans.
