56402-05-2Relevant academic research and scientific papers
Biferrocene triazole ligand and ion type metal complex and preparation method thereof
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Paragraph 0061; 0062; 0063, (2017/08/31)
The invention discloses a biferrocene triazole ligand and an ion type metal complex and a preparation method thereof. The biferrocene triazole ligand has a formula shown in the description; the energy-containing ion type metal complex with the ligand has a formula shown in the description, wherein in the formula, M is Cu, Co, Ni, Mn, Zn or Pb; when the L is the carbazotic acid monovalence anion, m is 1, and n is 4; when the L is styphnic acid diatomic anion, m is 1, and n is 2; when the L is the trinitrophloroglucinol trivalent anion, m is 3, and n is 4; r is the number of free water molecules in the compelx. The complex provided by the invention is not liable to volatilize under the natural condition; the thermal stability is high; high generation heat and combustion heat are realized; high combustion catalysis performance is realized on ammonium perchlorate. The preparation method of the complex has the advantages that the operation is simple and convenient; the target product yield is high.
