56430-88-7Relevant academic research and scientific papers
Mild and efficient method for-thiocyanation of ketones and-dicarbonyl compounds using bromodimethylsulfonium bromide-ammonium thiocyanate
Bhalerao, Dinesh S.,Akamanchi, Krishnacharya G.
, p. 799 - 807 (2010)
An efficient and convenient method for-thiocyanation of ketones and-dicarbonyl compounds has been developed using a reagent combination of bromodimethylsulfonium bromide (BDMS) and ammonium thiocyanate in acetonitrile. The developed method is mild and gave good yield of the products at room temperature.
A convenient, rapid, and general synthesis of α-oxo thiocyanates using clay supported ammonium thiocyanate
Meshram,Thakur, Pramod B.,Madhu Babu,Bangade, Vikas M.
experimental part, p. 1780 - 1785 (2012/05/04)
A very rapid, convenient, and general method for the synthesis of α-oxo thiocyanates has been described by using clay supported ammonium thiocyanate. The procedure avoids the use of additional catalyst, solvent, aqueous work-up and the yields are high. Moreover, the method is applicable for a variety of aryl, heteroaryl, alkyl α-halo carbonyls, β-keto tosylates, α-halo β-dicarbonyl, α-tosyl, β-dicarbonyl, alkyl halide, and alkyl tosylates.
Heteropoly acids as heterogeneous and reusable catalyst for α-thiocyanation of ketones
Chaskar, Atul C.,Yadav, Arun A.,Langi, Bhushan P.,Murugappan, Anita,Shah, Chetan
experimental part, p. 2850 - 2856 (2010/10/20)
Simple, efficient, and mild method for -thiocyanation of ketones in presence of heteropolyacid has been developed. This methodology offered -oxothiocyanates in good to excellent yields at room temperature in a highly selective manner. The catalyst could b
Oxone as a mild, inexpensive, and environmentally benign oxidant for the α-thiocyanation of ketones
Anil Kumar,Reddy, K. R. Kishore Kumar,Reddy, M. Veeranarayana,Reddy, C. Suresh,Reddy, C. Devendranath
, p. 2089 - 2095 (2008/09/21)
An efficient and direct approach for the α-thiocyanation of ketones with α-hydrogens has been developed using ammonium thiocyanate as a thiocyanating agent and oxone as an oxidant in methanol. Copyright Taylor & Francis Group, LLC.
Iron(III) chloride as mild and efficient reagent for the α-thiocyanation of ketones: An expedient synthesis of α-oxo thiocyanates
Yadav, Jhillu S.,Subba Reddy, Basi V.,Subba Reddy, Ummareddy V.,Chary, Darshanoju N.
, p. 1283 - 1287 (2008/12/22)
A simple and efficient method for the α-thiocyanation of ketones has been developed; anhydrous iron(III) chloride is used under mild conditions to produce αoxo thiocyanates in good to high yields and with high selectivity. The use of inexpensive and readi
