5649-96-7

Basic information

• Product Name: Bicyclo[10.2.2]hexadecane-1(14),12,15-triene
• Synonyms: [10]Paracyclophane;Bicyclo[10.2.2]hexadeca-1(14),12,15-triene;Bicyclo[10.2.2]hexadeca-12,14(1),15-triene;Bicyclo[10.2.2]hexadecane-1(14),12,15-triene
• CAS NO: 5649-96-7
• Molecular Formula: C₁₆H₂₄
• Molecular Weight: 216.36
• Mol File: 5649-96-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bicyclo[10.2.2]hexadecane-1(14),12,15-triene(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[10.2.2]hexadecane-1(14),12,15-triene(5649-96-7)
• EPA Substance Registry System: Bicyclo[10.2.2]hexadecane-1(14),12,15-triene(5649-96-7)

Safety Data

• Hazardous Substances Data: 5649-96-7(Hazardous Substances Data)

Upstream product

• 5732-39-8 spiro[[1,3]dithiane-2,5'-[10]paracyclophane] 
• 94929-97-2 1,4-(5-hydroxy-6-ketodecamethylene)benzene 
• 38877-45-1 [10]paracyclophan-1-one 
• 71-43-2 benzene 
• 53668-53-4 10-Phenyl-7-oxo-decansaeure 
• 98562-23-3 4-<4-(5-Valerianyloxymethyl)-benzoyl>-buttersaeure 
• 38877-44-0 10-phenyl-decanoyl chloride 
• 18017-73-7 10-phenyldecanoic acid 
• 20620-59-1 5-phenyl-n-valeric acid methyl ester 
• 202342-13-0 6-acetoxy-[10]paracyclophan-5-one 
• 101430-11-9 5-oxo-5,5'-p-phenylene-di-valeric acid 
• 23422-25-5 1,4-di(4'-carbomethoxy) butyl benzene 
• 23354-92-9 4,4'-p-phenylenebis(valeric acid) 
• 108-55-4 glutaric anhydride, 

Downstream Products

• 38877-62-2 Bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-trien-13-yl-carbamic acid benzyl ester 
• 284-67-3 cis-hexahydro-[10]paracyclophane 

Relevant articles and documents

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Arenes Disubstituted with Primary Alkyl Groups from Xylylene Dianions

Xylenes were converted into dianions 1.Reaction of dianions 1 with dialkyl sulfates gave symmetrical dialkylbenzenes 2 (R = R'), while methyl iodide caused oxidative coupling followed by alkylation to give 8.Unsymmetrical dialkylbenzenes 2 (R =/= R') were made by an indirect route involving monoanions 9 and 11.Reactions of dianions 1 with dihalides gave cyclophanes o-3 (n = 5,6,9), m-3 (n = 8-10), and p-3 (n = 9-11) and cyclophanes o-4 (n = 2,5,7,9) and m-4 (n = 2,6,7).Dianion 5 from 2,6-lutidine was used to prepare nitrogen analogues of 2 (R = R') and m-3 (n = 8-10).