565173-07-1

Basic information

• Product Name: TiBr₂(2,6-diphenylphenoxide)2
• CAS NO: 565173-07-1
• Molecular Weight: 698.289
• Mol File: 565173-07-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: TiBr₂(2,6-diphenylphenoxide)2(CAS DataBase Reference)
• NIST Chemistry Reference: TiBr₂(2,6-diphenylphenoxide)2(565173-07-1)
• EPA Substance Registry System: TiBr₂(2,6-diphenylphenoxide)2(565173-07-1)

Safety Data

• Hazardous Substances Data: 565173-07-1(Hazardous Substances Data)

Upstream product

• 2432-11-3 (1,1';3',1''-terphenyl)-2'-ol 
• 7789-68-6 titanium(IV) bromide 

Relevant articles and documents

The isolation and structure of titanium bromide compounds containing 2,6-diphenylphenoxide ligation; terminal and bridging ligand effects on Ti-Ti interactions

The titanium aryloxy bromides [Ti(OC6H3Ph 2-2,6)2Br2] 1 and [(2,6-Ph2C 6H3O)2Ti(μ-Br)2Ti(OC 6H3Ph2-2,6)2] 2 have been isolated and structurally characterized. Compound 1 adopts a pseudo-tetrahedral environment about titanium while 2 contains an edge-shared bis(tetrahedral) coordination geometry. The Ti-Ti distance is 3.0308(8) A in 2. A comparison of these compounds with their chloride counterparts as well as cyclopentadiene analogues has been made. The Ti-Ti distance in the compounds [Cp′2Ti(μ-X)2 TiCp′2] (Cp′) = methylcyclopentadienyl) increases as the bridging ligand X is changed from Cl to Br. In contrast this parameter is almost identical in the aryloxide compounds [(ArO)2Ti(μ-X)2Ti(OAr)2] (ArO = 2,6-diphenylphenoxide), due to the presence of a titanium-titanium bonding interaction. The Royal Society of Chemistry 2003.