565177-87-9Relevant academic research and scientific papers
Cobalt complexes bearing pyridine-imino ligands with bulky aryl substituents: Synthesis, characterization, and 1,3-butadiene polymerization behaviors
Guo, Jun,Zhang, Chunyu,Bi, Jifu,Zhang, Hexin,Bai, Chenxi,Hu, Yanming,Zhang, Xuequan
, p. 414 - 421 (2015)
A series of Co(II) complexes bearing pyridine-imino ligands [2-Ar1-6-(CMe = NAr2)C5H3N]CoCl2 (Ar1 = C6H5, Ar2 = 2,6-i-Pr2C6H3/su
Selective oligomerization of ethylene to linear α-olefins by tetrahedral cobalt(II) complexes with 6-(organyl)-2-(imino)pyridyl ligands: Influence of the heteroatom in the organyl group on the catalytic activity
Bianchini, Claudio,Mantovani, Giuseppe,Meli, Andrea,Migliacci, Fabio,Laschi, Franco
, p. 2545 - 2547 (2008/10/08)
The oligomerization of ethylene to α-olefins has been obtained by MAO activation of tetrahedral CoII complexes of iminopyridines substituted in the 6-position of the pyridine ring by thiophen-2-yl, furan-2-yl, or phenyl groups. An intriguing heteroatom effect has been noticed on both activity and selectivity, together with a change in the CoII spin state upon activation of the dichloride precursors with MAO.
