565222-95-9Relevant academic research and scientific papers
β-Fragmentation of primary alkoxyl radicals versus hydrogen abstraction: Synthesis of polyols and α,ω-differently substituted cyclic ethers from carbohydrates
Boto, Alicia,Hernandez, Dacil,Hernandez, Rosendo,Suarez, Ernesto
, p. 5310 - 5319 (2007/10/03)
The β-fragmentation of primary alkoxyl radicals, described in many cases as low-yielding and plagued by side reactions, can proceed in satisfactory yields using carbohydrate substrates. The only reaction that can compete significantly with the β-scission
