566198-10-5Relevant articles and documents
Electron Impact Induced Fragmentation of Aromatic Alkoxyimines II [5]. Formation and Transformation of Heterocyclic Radical Cations in the Gas Phase
Kaiser, Alexander,Mayer, Klaus K.,Sellmer, Andreas,Wiegrebe, Wolfgang
, p. 343 - 354 (2007/10/03)
The molecular ion 1 of N-(n-propoxy)benzaldimine I rearranges by an 1,5-H-shift to the δ-distonic ion 2 which subsequently cyclizes to the α-distonic ion 3. Homolytic cleavage of the N-O bond in 3 results in the δ-distonic ion 4 which expels CH2/sub