56638-60-9

Basic information

• Product Name: m-chloroanilinomethanesulfonate
• Synonyms: m-chloroanilinomethanesulfonate
• CAS NO: 56638-60-9
• Molecular Weight: 220.656
• Mol File: 56638-60-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: m-chloroanilinomethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: m-chloroanilinomethanesulfonate(56638-60-9)
• EPA Substance Registry System: m-chloroanilinomethanesulfonate(56638-60-9)

Safety Data

• Hazardous Substances Data: 56638-60-9(Hazardous Substances Data)

Upstream product

• 870-72-4 sodium formaldehyde bisulfite 
• 108-42-9 3-chloro-aniline 

Downstream Products

• 870-72-4 sodium formaldehyde bisulfite 
• 108-42-9 3-chloro-aniline 

Relevant articles and documents

MECHANISM OF AMINOMETHANESULFONATE FORMATION AND HYDROLYSIS REACTIONS

Based on kinetic, structural and synthetic evidence, a mechanism is proposed fro the synthesis of aminomethanesulfonates (R*NH*CHR'*SO3(1-)).The mechanism involves the initial protonation of the amine, proton transfer to the hydroxymethanesulfonate via a six-membered cyclic intermediate followed by a nucleophilic attack of the free amine on the carbon atom.The transition state is assumed to correspond to a structure with practically all the positive charge on the nitrogen atom.For the hydrolysis reaction, the initial protonation of the aminomethanesulfonate is followed by the nucleophilic attack of a water molecule.This mechanism is in agreement with the experimentally determined Hammett reaction constants ρ, i.e. -3.5 for the formation reaction and -2.3 for the hydrolysis.