56640-06-3

Upstream product

• 6742-26-3 2-ethoxycarbonyl-1-tetralone 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 100046-58-0 3,4-Dihydronaphthalin-2-carbonsaeure-ethylester 
• 100188-67-8 ethyl 1-hydroxy-1,2,3,4-tetrahydronaphthalene-2-carboxylate 
• 108638-33-1 3-bromomethyl-1,2,3,4-tetrahydronaphthalene 1,2-oxide 
• 2717-44-4 2-methyl-3,4-dihydronaphthalene 
• 100188-68-9 3-(bromomethyl)-1,2-dihydronaphthalene 
• 100046-59-1 3-(hydroxymethyl)-1,2-dihydronaphthalene 

Relevant academic research and scientific papers

Radical-induced cleavages in ring-fused epoxides

Carbon-carbon bond cleavage has been observed in ring-fused epoxides where stereoelectronic effects do not interfere.

Regioselectivity of Radical-induced Bond Cleavages in Epoxides

Radical-induced carbon-carbon and carbon-oxygen bond cleavage reactions in a highly substituted epoxide, and in epoxides fused to other rings are reported.Substitution at the site of the developing radical assists C-C bond cleavage.In ring-fused epoxides, C-C bond cleavage was not seen where stereoelectronic factors oppose it.

Novel Synthesis of Vinyl Ethers induced by Carbon-Halogen Bond Homolysis

Cleavage of 2-aryl-3-α-halogenoalkyloxiranes, brought about by tributylstannyl radicals, leads to products resulting from carbon-carbon bond cleavage.