566933-67-3Relevant academic research and scientific papers
Proton-induced change of the coordination mode of a boron group: Boryl complexes [Mn(CO)4(PR3)(BH2·PMe3) and cationic borane σ complexes [Mn(CO)4(PR3)(η1-BH3 ·PMe3)]
Yasue, Takahiro,Kawano, Yasuro,Shimoi, Mamoru
, p. 1727 - 1730 (2003)
Mode change on protonation: New borylmanganese complexes 1 undergo protonation to give cationic borane o complexes 2. Heterolytic cleavage of the metal-coordinated B-H bond was observed in the decomposition process of 2.
