56741-05-0Relevant articles and documents
KI-catalyzed synthesis of S-Thiocarbamates by cross-coupling of cyclohexyl isocyanide with sulfonyl chlorides
Lin, Liangwei,Fang, Zhengjun,Li, Yajun,Wu, Feng,Au, Chaktong,Luo, Sai
, p. 347 - 351 (2019)
A simple and efficient process for direct generation of various S-thiocarbamates is developed by cross-coupling of readily available sulfonyl chlorides with cyclohexyl isocyanide. The yields are excellent and the structures of the generated S-thiocarbamat
Electrochemical metal- And oxidant-free synthesis of S-thiocarbamates
Malviya, Bhanwar Kumar,Sharma, Siddharth,Verma, Ved Prakash
, p. 9491 - 9500 (2021/11/17)
An expeditious synthetic strategy to access functionalized S-thiocarbamates was developed in good to excellent yields and with high current efficiencies. Readily available isocyanides and thiols were used as the starting materials under simple metal- and oxidant-free reaction conditions avoiding an inert atmosphere. The practical application of the present methodology was achieved by electrochemical synthesis of the herbicides prosulfocarb and pebulate. Furthermore, continuous electrochemical flow conditions using a graphite/Pt flow cell were used to obtain S-thiocarbamate compounds on a gram scale within a residence time of 35 min. This journal is
Clean preparation of S-thiocarbamates with in situ generated hydroxide in 2-methyltetrahydrofuran
Bao, Wen-Hu,Wang, Zheng,Tang, Xiao,Zhang, Yun-Fu,Tan, Jia-Xi,Zhu, Qin,Cao, Zhong,Lin, Ying-Wu,He, Wei-Min
supporting information, p. 2259 - 2262 (2019/07/30)
A simple and clean protocol for the synthesis of various alkyl and (hetero)aryl S-thiocarbamates was established. The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a