569-15-3

Usage

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 28, p. 29, 1991 DOI: 10.1002/jhet.5570280105The Journal of Organic Chemistry, 42, p. 3463, 1977 DOI: 10.1021/jo00442a001

InChI:InChI=1/C14H8O2/c15-12-7-8-13(16)14-10-4-2-1-3-9(10)5-6-11(12)14/h1-8H

Upstream product

• 82650-72-4 1-bromo-4-benzoyloxyimino-1,2,3,4-tetrahydrophenanthrene 
• 85-01-8 phenanthrene 

Downstream Products

• 24903-46-6 Phenanthro<2,3-h>isoquinoline 
• 24903-48-8 phenanthro<3.2-h>isoquinoline 
• 133620-01-6 N-benzoyl-1,2,3,4,7,14-hexahydrophenanthro<3.2-h>isoquinoline 
• 133620-02-7 N-benzoyl-1,2,3,4,7,14-hexahydrophenanthroy<2.3-h>isoquinoline 
• 133619-99-5 N-Benzoyl-1,2,3,4-tetrahydrophenanthro<3.2-h>isoquinoline-7,14-dione 
• 133620-00-5 N-Benzoyl-1,2,3,4-tetrahydrophenanthro<2.3-h>isoquinoline-7,14-dione 
• 33929-61-2 1,4-diacetoxy-phenanthrene 

Relevant academic research and scientific papers

Photocatalytic degradation of polycyclic aromatic hydrocarbons in GaN:ZnO solid solution-assisted process: Direct hole oxidation mechanism

GaN:ZnO exhibits excellent activity for the photodegradation of PAHs, and the activity can be obviously improved by loading Pt. The degradation of PAHs in the system of GaN:ZnO is induced by the formation of holes. The holes generated then interact with PAHs to produce PAHs+, which is active enough to react with O2.

Chromium(VI) Based Oxidants; II. Zinc Dichromete Trihydrate: A Versatile and Mild Reagent for the Oxidation of Organic Compounds

Zinc dichromate trihydrate is an easily prepared, stable, and cheap reagent for the efficient oxidation of organic compounds in aprotic solvents at room temperature.

OXYGENATION OF AROMATIC AND ALIPHATIC HYDROCARBONS BY A NEW REAGENT SYSTEM, Fe(CH3CN)6(2+)-H2O2-Ac2O: AN EFFECTIVE MODEL REAGENT FOR MONO-OXYGENASE

Reactions of aromatic and aliphatic hydrocarbons with a new system, Fe(CH3CN)6(2+) - H2O2 - Ac2O in CH3CN, gave oxygenation products with fairly high reaction efficiency ( Tables I and II )compared to known to reagent systems used as enzyme models for mono-oxygenases.Investigations of the mechanism of these reactions indicated the involvement of either complex C.FeIV(OH)(OAc)(2+), or complex D, FeIV(OAc)(2+), dependig on the organic substrate.Keywords-oxygenation; aromatic hydrocarbon; aliphatic hydrocarbon; hexakisacetonitrile iron(II) perchlorate; hydrogen peroxide; enzyme model; mono-oxygenase

ATTEMPTS TO PREPARE AROMATIC O-ACYL-HYDROXYLAMINES-III0

From the reaction mixture of the dehydrobromination of 1-bromo-4-benzoyloxyimino-1,2,3,4-tetrahydrophenanthrene (1) with 1,8-diazabicycloundec-7ene (DBU) in benzene and in heavy atom solvents several products were isolated and their structures eluc