56914-94-4

Basic information

• Product Name: (3aR,4R,5R,7R,7aR)-5-Chloro-octahydro-4,7-methano-indene
• CAS NO: 56914-94-4
• Molecular Weight: 170.682
• Mol File: 56914-94-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3aR,4R,5R,7R,7aR)-5-Chloro-octahydro-4,7-methano-indene(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,4R,5R,7R,7aR)-5-Chloro-octahydro-4,7-methano-indene(56914-94-4)
• EPA Substance Registry System: (3aR,4R,5R,7R,7aR)-5-Chloro-octahydro-4,7-methano-indene(56914-94-4)

Safety Data

• Hazardous Substances Data: 56914-94-4(Hazardous Substances Data)

Upstream product

• 10271-42-8 Octahydro-endo-4,7-methanoinden-endo-5-ol 
• 10271-42-8 (3aRS,4RS,5RS,7RS,7aRS)-(±)-octahydro-1H-4,7-methanoinden-5-ol 

Downstream Products

• 80394-98-5 2-carboxy-exo-tetrahydrodicyclopentadiene 

Relevant articles and documents

ON THE REACTION OF ALCOHOLS WITH HALOCARBENES. ARE CARBOCATIONS INTERMEDIATES?

There is no evidence for hydride shift in the reaction of alcohols 1 and 2 with dichlorocarbene.Accordingly, the intermediate cannot be a free carbocation.It is suggested that the products are formed through a combination of SNi and direct displacement reactions in which tight ion pairs are involved.