Tetrahedron Letters p. 5089 - 5092 (1989)
Update date:2022-08-04
Topics:
Likhotvorik, Igor R.
Jones, Maitland
Yurchenko, Alexander G.
Krasutsky, Pavel A.
There is no evidence for hydride shift in the reaction of alcohols 1 and 2 with dichlorocarbene.Accordingly, the intermediate cannot be a free carbocation.It is suggested that the products are formed through a combination of SNi and direct displacement reactions in which tight ion pairs are involved.
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