ON THE REACTION OF ALCOHOLS WITH HALOCARBENES. ARE CARBOCATIONS INTERMEDIATES?

DOI: 10.1016/S0040-4039(01)93454-9

Source and publish data:

Tetrahedron Letters p. 5089 - 5092 (1989)

Update date:2022-08-04

Topics:

Authors:

Likhotvorik, Igor R.

Jones, Maitland

Yurchenko, Alexander G.

Krasutsky, Pavel A.

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Article abstract of DOI:10.1016/S0040-4039(01)93454-9

There is no evidence for hydride shift in the reaction of alcohols 1 and 2 with dichlorocarbene.Accordingly, the intermediate cannot be a free carbocation.It is suggested that the products are formed through a combination of S_Ni and direct displacement reactions in which tight ion pairs are involved.

Full text of DOI:10.1016/S0040-4039(01)93454-9

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