57016-93-0

Upstream product

• 54503-65-0 2,2-dimethyl-6-(trityloxymethyl)tetrahydrofuro[3,4-d][1,3]dioxol-4-ol 
• 76-83-5 trityl chloride 
• 532-20-7 D-Ribose 
• 67814-68-0 2,3-O-isopropylidene-β-D-ribofuranose 
• 58166-67-9 2,3-O-Isopropylidene-5-O-trityl-α,β-ribofuranosyl chloride 
• 58109-10-7 ethyl 3-propiolate silver salt 

Downstream Products

• 85357-22-8 ((3aS,4R,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-propynal 
• 199996-84-4 2-((3aS,4R,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-pyrazolo[1,5-a]pyridine-3-carboxylic acid ethyl ester 
• 199996-88-8 3-Benzoyl-2-((3aS,4R,6R,6aR)-2,2-dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-indolizine-1-carboxylic acid ethyl ester 

Relevant academic research and scientific papers

Syntheses of anomeric pairs of new C-nucleosides via 1,3-dipolar cycloaddition reaction, part I

A convenient pathway to a variety of β-and α-C-nucleosides has been developed by utilizing 1,3-dipolar cycloaddition reactions of various exocyclic and endocyclic heterocyclic ylides with β (5a) and α (5b) anomers of ethyl 3-(2',3'-O-isopropylidene-5'-O-trityl-D-ribofuranosyl) propiolate, respectively. Assignment of configuration at C1' position of the C-nucleosides could be made by a comparative study of the properties of corresponding α and β anomers with a reasonable degree of certainity.