58166-67-9

Basic information

• Product Name: 2,3-O-Isopropylidene-5-O-trityl-α,β-ribofuranosyl chloride
• Synonyms: 2,3-O-Isopropylidene-5-O-trityl-α,β-ribofuranosyl chloride
• CAS NO: 58166-67-9
• Molecular Weight: 450.962
• Mol File: 58166-67-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-O-Isopropylidene-5-O-trityl-α,β-ribofuranosyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-O-Isopropylidene-5-O-trityl-α,β-ribofuranosyl chloride(58166-67-9)
• EPA Substance Registry System: 2,3-O-Isopropylidene-5-O-trityl-α,β-ribofuranosyl chloride(58166-67-9)

Safety Data

• Hazardous Substances Data: 58166-67-9(Hazardous Substances Data)

Upstream product

• 67814-68-0 2,3-O-isopropylidene-β-D-ribofuranose 
• 532-20-7 D-Ribose 
• 76-83-5 trityl chloride 

Downstream Products

• 154096-13-6 (2R,3S)-3-(benzyloxy)-2-((benzyloxy)methyl)-2,3-dihydrofuran 
• 175470-37-8 N¹-(5-O-trityl-2,3-O-isopropylidene-α-D-ribofuranosyl)inosine 
• 57016-93-0 ((3aS,4R,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-propynoic acid ethyl ester 
• 57016-91-8 O⁵,O⁶-isopropylidene-O⁸-trityl-D-allo-4,7-anhydro-2,3-dideoxy-oct-2-ynonic acid ethyl ester 
• 99232-86-7 (R)-2-(2,4-dimethoxy-5-nitropyrimidin-6-yl)-2-(2,3-O-isopropylidene-5-O-(triphenylmethyl)-α-D-ribofuranosyl)acetonitrile 
• 99232-87-8 (S)-2-(2,4-dimethoxy-5-nitropyrimidin-6-yl)-2-(2,3-O-isopropylidene-5-O-(triphenylmethyl)-α-D-ribofuranosyl)acetonitrile 
• 96761-00-1 1,4-anhydro-2-deoxy-D-erythro-pent-1-enitol 
• 199996-83-3 2-((3aS,4S,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-pyrazolo[1,5-a]pyridine-3-carboxylic acid ethyl ester 
• 199996-84-4 2-((3aS,4R,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-pyrazolo[1,5-a]pyridine-3-carboxylic acid ethyl ester 
• 199996-92-4 4-((3aS,4S,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-1-methyl-5-phenyl-1H-pyrrole-2,3-dicarboxylic acid diethyl ester 
• 199996-93-5 4-((3aS,4R,6R,6aR)-2,2-Dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-1-methyl-5-phenyl-1H-pyrrole-2,3-dicarboxylic acid diethyl ester 
• 199996-87-7 3-Benzoyl-2-((3aS,4S,6R,6aR)-2,2-dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-indolizine-1-carboxylic acid ethyl ester 
• 199996-88-8 3-Benzoyl-2-((3aS,4R,6R,6aR)-2,2-dimethyl-6-trityloxymethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-indolizine-1-carboxylic acid ethyl ester 

Relevant articles and documents

Syntheses of anomeric pairs of new C-nucleosides via 1,3-dipolar cycloaddition reaction, part I

A convenient pathway to a variety of β-and α-C-nucleosides has been developed by utilizing 1,3-dipolar cycloaddition reactions of various exocyclic and endocyclic heterocyclic ylides with β (5a) and α (5b) anomers of ethyl 3-(2',3'-O-isopropylidene-5'-O-trityl-D-ribofuranosyl) propiolate, respectively. Assignment of configuration at C1' position of the C-nucleosides could be made by a comparative study of the properties of corresponding α and β anomers with a reasonable degree of certainity.