57051-07-7Relevant articles and documents
Hypercoordination of aluminum: Evidence for the implication of pentacoordinate complexes in the R2AlCl-promoted reduction of alkoxycarbonyl substrates
Ooi, Takashi,Morikawa, Junko,Uraguchi, Daisuke,Maruoka, Keiji
, p. 2993 - 2996 (1999)
R2AlCl-promoted reductions of alkoxycarbonyl substrates with Bu3SnH were found to proceed diastereoselectively through the formation of pentacoordinate chelate-type complexes which have been characterized by 13C NMR spectr
Stereoselective Reduction of α-Methyl-β-hydroxy Ketones with Zinc Borohydride
Nakata, Tadashi,Tani, Yoichiro,Hatozaki, Masayoshi,Oishi, Takeshi
, p. 1411 - 1415 (2007/10/02)
Zinc borohydride reduction of α-methyl-β-hydroxy ketones 3 produced the erythro-2-methyl-1,3-glycol derivatives 4 with high stereoselectivity.The selectivity was particularly high when an olefinic group was conjugated to the carbonyl group.Reduction of th