Hypercoordination of aluminum: Evidence for the implication of pentacoordinate complexes in the R2AlCl-promoted reduction of alkoxycarbonyl substrates

DOI: 10.1016/S0040-4039(99)00401-3

Source and publish data:

Tetrahedron Letters p. 2993 - 2996 (1999)

Update date:2022-08-05

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Authors:

Ooi, Takashi

Morikawa, Junko

Uraguchi, Daisuke

Maruoka, Keiji

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Article abstract of DOI:10.1016/S0040-4039(99)00401-3

R₂AlCl-promoted reductions of alkoxycarbonyl substrates with Bu₃SnH were found to proceed diastereoselectively through the formation of pentacoordinate chelate-type complexes which have been characterized by ¹³C NMR spectr

Full text of DOI:10.1016/S0040-4039(99)00401-3

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