57057-05-3Relevant academic research and scientific papers
Base-mediated tandem reaction of α-aryloxyacetophenones with phosphonates: Selective synthesis of enol phosphates
Song, Ren-Jie,Liu, Yan-Yun,Wu, Ji-Cheng,Xie, Ye-Xiang,Deng, Guo-Bo,Yang, Xu-Heng,Liu, Yu,Li, Jin-Heng
experimental part, p. 1119 - 1125 (2012/05/04)
A new, simple method for the synthesis of enol phosphates by base-mediated tandem reaction of α-aryloxyacetophenones with phosphonates is described. In the presence of Cs2CO3, a variety of -aryloxyacetophenones smoothly underwent the sequential O-P bond-forming/C-O bond cleavage/isomerization tandem reaction with phosphonates at room temperature, providing the corresponding enol phosphates in moderate to excellent yields. Georg Thieme Verlag Stuttgart · New York.
