571167-47-0

Basic information

• Product Name: 8-Oxabicyclo[3.2.1]oct-3-en-2-ol, 3-ethyl-, (1R,2R,5S)-rel- (9CI)
• Synonyms: 8-Oxabicyclo[3.2.1]oct-3-en-2-ol, 3-ethyl-, (1R,2R,5S)-rel- (9CI)
• CAS NO: 571167-47-0
• Molecular Formula: C9H14O2
• Molecular Weight: 154.20626
• Product Categories: ALCOHOL
• Mol File: 571167-47-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 8-Oxabicyclo[3.2.1]oct-3-en-2-ol, 3-ethyl-, (1R,2R,5S)-rel- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 8-Oxabicyclo[3.2.1]oct-3-en-2-ol, 3-ethyl-, (1R,2R,5S)-rel- (9CI)(571167-47-0)
• EPA Substance Registry System: 8-Oxabicyclo[3.2.1]oct-3-en-2-ol, 3-ethyl-, (1R,2R,5S)-rel- (9CI)(571167-47-0)

Safety Data

• Hazardous Substances Data: 571167-47-0(Hazardous Substances Data)

Upstream product

• 676-58-4 methylmagnesium chloride 

Relevant articles and documents

Copper-catalysed addition of organometallic reagents to vinyl diepoxides - A novel route to oxa-bridged systems and to substituted allylic alcohols

The copper-catalysed addition of organometallic reagents (Grignard and dialkylzinc) to new vinyl diepoxides was examined. Cyclic vinyl diepoxides undergo clean SN2′ reactions to afford oxa-bridged systems of various sizes after a domino intramolecular O-alkylation reaction. Acyclic vinyl diepoxides are alkylated in good yields and with good regioselectivities, and a new catalytic enantioselective desymmetrization reaction to afford an enantioenriched allylic epoxy alcohol by the use of catalytic amounts of a copper phosphorarnidite complex was demonstrated. Remarkable differences in terms of reactivity and selectivity are found when different organocopper reagents, generated in situ, are employed. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.