57124-78-4Relevant academic research and scientific papers
Novel ambiphilic dichlorocarbenoid equivalent in alkene cyclopropanation and carbonyl olefination
Chien, Ching-Ting,Tsai, Chia-Chung,Tsai, Chi-Hui,Chang, Tsai-Yuan,Tsai, Ping-Kuei,Wang, Ying-Chuan,Yan, Tu-Hsin
, p. 4324 - 4327 (2006)
The Ti-Mg-dichloromethylene complexes derived from the oxidative addition of CCl4 to the Mg-TiCl4 bimetallic species serve as a novel class of ambiphilic dichlorocarbenoid equivalents. Not only is Ti-Mg-dichlorocarbenoid highly selective but also it seems highly reactive in both alkene cyclopropanations and carbonyl dichloromethylenations.
