5445-30-7

Basic information

• Product Name: 1-N-BUTYLCYCLOHEXANOL
• Synonyms: Cyclohexanol, 1-butyl-;1-BUTYLCYCLOHEXANOL;1-N-BUTYLCYCLOHEXANOL;1-n-Butylcyclohexanol,98%;1-Butyl-1-cyclohexanol;1-butylcyclohexan-1-ol
• CAS NO: 5445-30-7
• Molecular Formula: C₁₀H₂₀O
• Molecular Weight: 156.27
• Mol File: 5445-30-7.mol
• Article Data: 26

Chemical Properties

• Boiling Point: 210.9°Cat760mmHg
• Flash Point: 84.6°C
• Appearance: /
• Density: 0.906g/cm³
• Vapor Pressure: 0.0425mmHg at 25°C
• Refractive Index: 1.465
• CAS DataBase Reference: 1-N-BUTYLCYCLOHEXANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 1-N-BUTYLCYCLOHEXANOL(5445-30-7)
• EPA Substance Registry System: 1-N-BUTYLCYCLOHEXANOL(5445-30-7)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 5445-30-7(Hazardous Substances Data)

Usage

Uses

Intermediates of Liquid Crystals

Synthesis Reference(s)

Journal of the American Chemical Society, 102, p. 7926, 1980 DOI: 10.1021/ja00547a016

InChI:InChI=1/C10H20O/c1-2-3-7-10(11)8-5-4-6-9-10/h11H,2-9H2,1H3

Upstream product

• 177-10-6 1,3-dioxolane-2-spirocyclohexane 
• 109-72-8 n-butyllithium 
• 54637-77-3 potassium cyclohexanolate 
• 513-37-1 2-methylprop-1-enyl chloride 
• 53282-30-7 trifluoro-methanesulfonic acid 2-methyl-propenyl ester 
• 542-69-8 1-iodo-butane 
• 108-94-1 cyclohexanone 
• 109-69-3 n-Butyl chloride 
• 693-04-9 butyl magnesium bromide 
• 2696-22-2 1-vinylethynyl-1-cyclohexanol 
• 627-32-7 1-iodopropan-3-ol 
• 300807-70-9 3-iodo-2-methylpropan-1-ol 
• 693-03-8 n-butyl magnesium bromide 
• 25542-62-5 6-bromo-hexanoic acid ethyl ester 

Downstream Products

• 5009-92-7 1-methyl-1-butylcyclohexane 
• 90975-16-9 2-methyl-5-pentamethylenetetrahydrofuran 
• 65727-40-4 dec-9-en-5-one 
• 108-94-1 cyclohexanone 
• 73061-26-4 1-(3-Hydroxybutyl)cyclohexanol 
• 1454679-85-6 1-butylcyclohexylhydroperoxide 
• 1133062-80-2 1-butylcyclohexyl dibenzyl phosphate 
• 2626-61-1 1-butylcyclohexylamine 
• 4144-60-9 6-oxodecanoic acid 
• 3282-53-9 1-butyl-1-cyclohexene 

Relevant articles and documents

Electrophotochemical Ring-Opening Bromination oftert-Cycloalkanols

An electrophotochemical ring-opening bromination of unstrainedtert-cycloalkanols has been developed. This electrophotochemical method enables the oxidative transformation of cycloalkanols with 5- to 7-membered rings into synthetically useful ω-bromoketones without the use of chemical oxidants or transition-metal catalysts. Alkoxy radical species would be key intermediates in the present transformation, which generate through homolysis of the O-Br bond in hypobromite intermediates under visible light irradiation.

Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides

We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carboncentered radicals with molecular oxygen.

Utility of neodymium diiodide as a reductant in ketone coupling reactions

Matrix presented The viability of Ndl2 as a one-electron reducing agent in organic synthesis has been examined by studying coupling reactions between alkyl chlorides and ketones and aldehydes.