57160-05-1Relevant academic research and scientific papers
Addition of dibromocarbene to cyclobutene: Characterisation and mechanism of formation of the products
Algi, Fatih,Hoekelek, Tuncer,Balci, Metin
, p. 658 - 660 (2007/10/03)
Cyclobutene reacted with dibromocarbene in solution to give 1,5-dibromocyclopent-1-ene (9), 1,2,6, 6-tetrabromobicyclo[3.1.0]hexane (10), and 1,2,3,6-tetrabromocyclohex-1-ene (11), in a ratio of 1:4:8, respectively. Compounds 10 and 11 were found to be formed from a second carbene addition and rearrangement under the given reaction conditions.
Radical Bromination of Cyclohexene in CCl4 by Bromine: Addition versus Substitution
McMillen, D. W.,Grutzner, John B.
, p. 4516 - 4528 (2007/10/02)
The radical reaction of bromine (1E-2 - 1E-5 M) with cyclohexene in CCl4 in the light has been investigated.The reactions have been found to be highly reversible and controlled by both thermodynamics and the availability of Br2 and HBr as equilibrating ag
