Optically Active Arsenic Macrocycles. Stereospecific Syntheses of Enantiomers and Diastereomers of 14-Membered trans As2S2 Chelating Macrocycles Containing Resolved Asymmetric Tertiary Arsine Donors

DOI: 10.1021/ja00248a030

Source and publish data:

Journal of the American Chemical Society p. 4321 - 4328 (1987)

Update date:2022-08-03

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Authors:

Kerr, Philip G.

Leung, Pak-Hing

Wild, S. Bruce

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Article abstract of DOI:10.1021/ja00248a030

The first optically active macrocycles containing arsenic, (R,R)- and (S,S)-1, have been synthesized by template dimerizations of the enantiomers of deprotonated (+/-)-(2-mercaptoethyl)<2-(methoxymethyl)phenyl>methylarsine, (+/-)-3, on palladium(II) with

Full text of DOI:10.1021/ja00248a030

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