57182-15-7

Upstream product

• 39627-97-9 2,2-dimethyl-N-(2,6-dimethylphenyl)propionamide 
• 3282-30-2 pivaloyl chloride 
• 87-62-7 2,6-dimethylaniline 

Downstream Products

• 57182-22-6 N-(2,6-Dimethyl-phenyl)-2,2-dimethyl-propionimidoyl isothiocyanate 
• 200886-78-8 3-[(Z)-2,6-Dimethyl-phenylimino]-2,2-dimethyl-undecan-4-one 
• 200886-77-7 2-[(Z)-2,6-Dimethyl-phenylimino]-3,3-dimethyl-butyric acid ethyl ester 
• 200886-76-6 1-{1-[(Z)-2,6-Dimethyl-phenylimino]-2,2-dimethyl-propyl}-cyclohexanol 
• 200886-74-4 2-[(Z)-2,6-Dimethyl-phenylimino]-3,3-dimethyl-1-phenyl-butan-1-ol 
• 1119821-66-7 C₂₇H₃₈N₂ 
• 85385-10-0 3,3-dimethyl-2-(2,6-dimethylphenylimino)butane 
• 1351994-92-7 1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene 

Relevant academic research and scientific papers

Triketiminate bis(borohydride) complexes of rare-earth metals [(2,6-Me2C6H3N=CMe)2C(2,6-Me2C6H3N=CBut)]Ln(BH4)2(THF)2 (Ln = Y, Nd): sy

A new triketimine (2,6-Me2C6H3N=CMe)2CH(2,6-Me2C6H3N=CBut) (1) was synthesized by the reaction of imidoyl chloride 2,6-Me2C6H3N=CClBu

Copper-nitrene complexes in catalytic C-H amination

(Chemical Equation Presented) Hydrocarbons activate! Isolable β-diketiminato dicopper-nitrene complexes such as 1 derived from the reaction of [{(Cl2NN)Cu}2(μ-benzene)] and 1-adamantylazide are potent towards nitrene insertion into unactivated sp 3-hybridized C-H bonds. 1 allows stoichiometric and catalytic intermolecular C-H amination of hydrocarbons to give secondary amines (see scheme). Catalyst loadings as low as 0.05 mol% may be used.

Imidoyl chlorides as starting materials for the preparation of masked acyllithium intermediates: Synthetic applications

The lithiation of several imidoyl chlorides 5, catalysed by substoichiometric amounts of naphthalene, followed by reaction with different electrophiles gives, after hydrolysis, the corresponding imine derivatives 6 and 9 or amines 7, depending on the reac