57182-15-7Relevant articles and documents
Triketiminate bis(borohydride) complexes of rare-earth metals [(2,6-Me2C6H3N=CMe)2C(2,6-Me2C6H3N=CBut)]Ln(BH4)2(THF)2 (Ln = Y, Nd): sy
Skvortsov,Cherkasov,Trifonov
, p. 1665 - 1674 (2017)
A new triketimine (2,6-Me2C6H3N=CMe)2CH(2,6-Me2C6H3N=CBut) (1) was synthesized by the reaction of imidoyl chloride 2,6-Me2C6H3N=CClBu
Copper-nitrene complexes in catalytic C-H amination
Badiei, Yosra M.,Dinescu, Adriana,Dai, Xuliang,Palomino, Robert M.,Heinemann, Frank W.,Cundari, Thomas R.,Warren, Timothy H.
supporting information; experimental part, p. 9961 - 9964 (2009/05/07)
(Chemical Equation Presented) Hydrocarbons activate! Isolable β-diketiminato dicopper-nitrene complexes such as 1 derived from the reaction of [{(Cl2NN)Cu}2(μ-benzene)] and 1-adamantylazide are potent towards nitrene insertion into unactivated sp 3-hybridized C-H bonds. 1 allows stoichiometric and catalytic intermolecular C-H amination of hydrocarbons to give secondary amines (see scheme). Catalyst loadings as low as 0.05 mol% may be used.
Imidoyl chlorides as starting materials for the preparation of masked acyllithium intermediates: Synthetic applications
Alonso, Emma,Ramon, Diego J.,Yus, Miguel
, p. 12007 - 12028 (2007/10/03)
The lithiation of several imidoyl chlorides 5, catalysed by substoichiometric amounts of naphthalene, followed by reaction with different electrophiles gives, after hydrolysis, the corresponding imine derivatives 6 and 9 or amines 7, depending on the reac