57204-41-8Relevant academic research and scientific papers
Resolution of the non-steady-state kinetics of the elimination of HBr from 2-(p-nitrophenyl)ethyl bromide in alcohol/alkoxide media
Handoo, Kishan L.,Lu, Yun,Zhao, Yixing,Parker, Vernon D.
, p. 24 - 26 (2007/10/03)
Non-steady-state kinetic studies reveal that the elimination of HBr from 2-(p-nitrophenyl)ethyl bromide in alcohol/alkoxide media, the classical concerted E2 reaction, actually takes place by a two-step mechanism involving the intermediate formation of th
Mechanism of elimination rections. 40. Attempted study of stereochemistry of elimination from 2-(p-nitrophenyl)ethyltrimmethylammonium ion. Base-promoted cis-trans isomerization of p-nitrostyrene-β-d1
Dohner, Brent R.,Saunders, William H., Jr.
, p. 1026 - 1030 (2007/10/02)
Stereospecifically deuterated ArCHDCHDNMe3+I- and ArCHDCHDNMe2O have been prepared, where Ar=C6H5 and p-NO2C6H4.When Ar=C6H5, the elimination reaction of the quaternery salt with ethoxide in ethanol goes with >98percent anti stereoch
On the Electron Impact Induced Hydroxyl Loss from o-Nitrostyrene
Depke, Gisbert,Klose, Walter,Schwarz, Helmut,Blum, Wolfgang,Richter, Wilhelm J.
, p. 568 - 571 (2007/10/02)
Unimolecular hydroxyl (OD.) loss form regio- and stereo-specifically labelled o-nitrostyrenes 1a, 1c and 1d results in the formation of an ion which upon collisional activation gives identical mass spectra.Suggestions are made which aim at explaining: (i) the loss of stereochemical integrity of the diastereotopic methylene hydrogens in the course of hydroxyl elimination; and (ii) to account for the collision induced losses of CO and HCN from the (1+) ion.
