57239-49-3Relevant academic research and scientific papers
(1-Selenocyanatoethyl)benzene: A Selenocyanation Reagent for Site-Selective Selenocyanation of Inert Alkyl C(sp3)-H Bonds
Yu, Fei,Li, Chuang,Wang, Chuangye,Zhang, Hongwei,Cao, Zhong-Yan
supporting information, p. 7156 - 7160 (2021/09/18)
A new, simple, yet easily accessible, (1-selenocyanatoethyl)benzene has been designed and applied as a SeCN group transfer reagent for selenocyanation of aliphatic C(sp3)-H bonds for the first time. This protocol is featured with mild reaction conditions and wide substrate scope. Control experiments reveal that a radical-group transfer mechanism might be involved.
Synthesis of Monofluoromethyl Selenoethers of Aryl and Alkyl from Organoselenocyanate via One-Pot Reaction
Cao, Yuan,Jiang, Lvqi,Yi, Wenbin
supporting information, p. 4360 - 4368 (2019/08/01)
The first practical and feasible approach for the monofluoromethylselenolation of aryl and alkyl halides via one-pot multistep synthesis using KSeCN and ICFH2 is described. Good yields and broad functional group compatibility were obtained. The successful preparation of monofluoromethylselenolated drug-like compounds good practicability of this method. This protocol offered a number of new monofluoromethyl selenoethers, which would accelerate the use of such compounds in the areas of life science. (Figure presented.).
Pronounced activity of aromatic selenocyanates against multidrug resistant ESKAPE bacteria
Nasim, Muhammad Jawad,Witek, Karolina,Kincses, Annamária,Abdin, Ahmad Yaman,?es?awska, Ewa,Mar?, Ma?gorzata Anna,Gajdács, Márió,Spengler, Gabriella,Nitek, Wojciech,Latacz, Gniewomir,Karczewska, El?bieta,Kie?-Kononowicz, Katarzyna,Handzlik, Jadwiga,Jacob, Claus
supporting information, p. 6021 - 6031 (2019/04/16)
Selenocyanates represent an interesting class of organic selenium compounds. Due to their similarity with better known natural (iso-)thiocyanates, they promise high biological activity and may also be metabolized to other Reactive Selenium Species (RSeS),
Selenocyanation using a combined reagent of triphenylphosphine and selenocyanogen. A new and simple synthesis of alkyl selenocyanates and symmetrical alkyl diselenides from alcohols
Tamura,Adachi,Kawasaki,Kita
, p. 2251 - 2252 (2007/10/12)
A novel reagent Ph3SeCN)2, easily prepared by adding an equimolar amount of tri-phenylphosphine to selenocyanogen solution in methylene chloride and tetrahydrofuran reacts below -60° with primary alcohols to produce directly the corr
