57261-22-0 Usage
Structure
Hexadiene chain with a bromine atom at the 6th position
Explanation
The IUPAC name follows a specific nomenclature system for organic compounds. In this case, it indicates a hexadiene with double bonds between the 1st and 3rd carbon atoms, a bromine atom at the 6th position, and the (3E)notation specifies the geometry of the double bond as being in the E (entgegen) configuration.
Explanation
Synonyms are alternative names for the same compound. In this case, "6-bromo-1,3-hexadiene" is another name for the compound, emphasizing the bromine atom's position in the molecule.
Explanation
The compound is classified as an alkene derivative because it is derived from an alkene (a hydrocarbon with one or more carbon-carbon double bonds) by the addition of a bromine atom.
Explanation
Due to its unique structure and reactivity, 1,3-Hexadiene, 6-bromo-, (3E)is used as a reagent in various organic synthesis processes and chemical reactions, contributing to the formation of different compounds.
Explanation
The compound's properties make it useful in a range of industrial applications, including the production of chemicals, materials, and other products.
Explanation
The compound's unique structure and reactivity also make it a candidate for use in the development of new drugs and agrochemicals, which could have various applications in medicine and agriculture.
Synonyms
6-bromo-1,3-hexadiene
Classification
Alkene derivative
Applications
Reagent in organic synthesis and chemical reactions
Industrial Processes
Valuable in various industrial processes
Potential Applications
Development of new pharmaceuticals and agrochemicals
Check Digit Verification of cas no
The CAS Registry Mumber 57261-22-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,7,2,6 and 1 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 57261-22:
(7*5)+(6*7)+(5*2)+(4*6)+(3*1)+(2*2)+(1*2)=120
120 % 10 = 0
So 57261-22-0 is a valid CAS Registry Number.
57261-22-0Relevant academic research and scientific papers
Buszek,Buszek, Keith R.
, p. 9125 - 9128 (1995)
The first intramolecular benzyne Diels-Alder reaction with an acyclic diene is reported. The course of the reaction is dependent on the diene geometry. Trans dienes afforded [4+2] cycloadducts; cis dienes apparently give [2+2] cycloadducts followed by further rearrangement, a mechanistic course which is supported by deuterium labeling experiments.
Rh(i)-Catalyzed enantioselective and scalable [4 + 2] cycloaddition of 1,3-dienes with dialkyl acetylenedicarboxylates
Bao, Robert Li-Yuan,Yin, Junjie,Shi, Lei,Zheng, Limin
supporting information, p. 2956 - 2961 (2020/04/28)
An asymmetric intermolecular [4 + 2] cycloaddition of 1,3-dienes with dialkyl acetylenedicarboxylates, which was catalyzed by a rhodium(i)-chiral phosphoramidite complex, was developed. This protocol provided a highly enantioselective access to prepare carbonyl substituted cyclohexa-1,4-dienes with up to 96% yield and >99% ee. Notably, a cycloaddition on the 10 g scale gave the product in 92% yield and with 99% ee, which showed great potential for the scale-up synthesis of carbonyl substituted cyclohexa-1,4-dienes. In addition, oxidative aromatizations and hydrolysis of the products were also investigated.
