Tetrahedron Letters p. 9125 - 9128 (1995)
Update date:2022-09-26
Topics:
Buszek
Buszek, Keith R.
The first intramolecular benzyne Diels-Alder reaction with an acyclic diene is reported. The course of the reaction is dependent on the diene geometry. Trans dienes afforded [4+2] cycloadducts; cis dienes apparently give [2+2] cycloadducts followed by further rearrangement, a mechanistic course which is supported by deuterium labeling experiments.
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