57266-59-8Relevant academic research and scientific papers
Synthesis and structures of fused N-heterocylic carbenes and their rhodium complexes
Li, Jean,Stewart, Ian C.,Grubbs, Robert H.
scheme or table, p. 3765 - 3768 (2010/12/20)
New procedures for the synthesis of N-heterocyclic carbenes with multiple fused rings have been developed utilizing a key ring-closing metathesis step. Rhodium complexes were obtained via the pentafluorophenyl carbene adducts. Solid-state structural behav
Synthesis of N-heterocyclic compounds via ene-yne metathesis reactions
Groaz, Elisabetta,Banti, Donatella,North, Michael
, p. 204 - 218 (2008/03/28)
Propargylamino and allylamino derivatives of cyclohexene and norbornene were subjected to tandem metathesis reactions with first and second generation Grubbs' catalysts 1 and 2. Results show that the method is compatible with suitably protected nitrogen-containing compounds. Cyclohexenes gave intriguing results in terms of the possibility to perform ring rearrangement metathesis (RRM) reactions, showing a difference with the analogous allyl and propargyl ether substrates.
Stereocontrolled Syntheses for the Six Diastereomeric 1,2-Dihydroxy-4,5-diaminocyclohexanes: PtII Complexes and P-388 Antitumor Properties
Witiak, Donald T.,Rotella, David P.,Filppi, Joyce A.,Gallucci, Judith
, p. 1327 - 1336 (2007/10/02)
Stereocontrolled syntheses for the six diastereomeric 1,2-dihydroxy-4,5-diaminocyclohexanes 3a-f from cyclohexene diamines cis-4 and trans-5 are described.Cbz-protected species cis-9 and trans-11, respectively, served as a source of stable Cbz-protected p
