57266-64-5Relevant academic research and scientific papers
Synthesis of N-heterocyclic compounds via ene-yne metathesis reactions
Groaz, Elisabetta,Banti, Donatella,North, Michael
, p. 204 - 218 (2008/03/28)
Propargylamino and allylamino derivatives of cyclohexene and norbornene were subjected to tandem metathesis reactions with first and second generation Grubbs' catalysts 1 and 2. Results show that the method is compatible with suitably protected nitrogen-containing compounds. Cyclohexenes gave intriguing results in terms of the possibility to perform ring rearrangement metathesis (RRM) reactions, showing a difference with the analogous allyl and propargyl ether substrates.
Noncovalent secondary interactions in Co(II)salen complexes: O2 binding and catalytic activity in cyclohexene oxygenation
Fiammengo, Roberto,Bruinink, Christiaan M.,Crego-Calama, Mercedes,Reinhoudt, David N.
, p. 8552 - 8557 (2007/10/03)
The O2 affinity of Co(II)Salen complexes 1-4 and their reactivity in cyclohexene oxygenation reactions of Co(II)Salen complexes 1-4 are modulated by noncovalent interactions such as hydrogen bonding and steric hindrance using a functionalized diamino bridge. Higher O2 affinity is observed in the case of efficient hydrogen-bonding interactions (complex 1), while increased steric hindrance (cis vs trans diamino bridge) around the Co-coordinated O2 is influencing the reactivity of the complexes.
