57272-88-5Relevant academic research and scientific papers
THE STEREOCHEMICAL OUTCOME OF DIENE ADDITIONS TO THIONITROSOARENES (ArN=S)
Bryce, Martin R.,Taylor, Paul C.
, p. 3835 - 3836 (1989)
Thionitrosoarenes (ArN=S) react efficiently with (E,E)- and (E,Z)-hexadienes to yield 1,2-thiazine adducts in which the stereochemistry of the diene is retained.
Skeletal scrambling of sulphur diimide radical anions
Bestari, Ketut,Oakley, Richard T.,Cordes, A. Wallace
, p. 94 - 99 (2007/10/02)
In the presence of a catalytic quantity of alkali metal mixtures of sulphur diimides RNSNR and R'NSNR' (R, R' = Ph, 4-C6H4Me, 4-C6H4OMe, SiMe3, SPh) undergo a rapid scrambling of the R and R' groups.When R and R' are significantly different (e.g., R = Ph,
