13165-69-0

Basic information

• Product Name: 4-Methoxy-N-sulfinylaniline
• Synonyms: 4-Methoxy-N-sulfinylaniline;1-methoxy-4-(sulfinylamino)benzene
• CAS NO: 13165-69-0
• Molecular Formula: C₇H₇NO₂S
• Molecular Weight: 169.2
• Mol File: 13165-69-0.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 260.8°Cat760mmHg
• Flash Point: 111.5°C
• Appearance: /
• Density: 1.21g/cm³
• Vapor Pressure: 0.0195mmHg at 25°C
• Refractive Index: 1.564
• CAS DataBase Reference: 4-Methoxy-N-sulfinylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methoxy-N-sulfinylaniline(13165-69-0)
• EPA Substance Registry System: 4-Methoxy-N-sulfinylaniline(13165-69-0)

Safety Data

• Hazardous Substances Data: 13165-69-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H7NO2S/c1-10-7-4-2-6(3-5-7)8-11-9/h2-5H,1H3

Upstream product

• 104-94-9 4-methoxy-aniline 
• 76541-52-1 N-(chlorosulfinyl)imidazole 

Downstream Products

• 5455-02-7 9-<(4-methoxyphenyl)imino>fluorene 
• 1344680-04-1 (R)-1-(4-methoxyphenylamino)-2-phenylbutane-2-thiol 
• 1344679-89-5 (1R,4S)-N-(4-methoxyphenyl)-4-ethyl-4-phenyl-1,2-thiazetidin-3-one 1-oxide 
• 1344680-07-4 (1S,4R)-N-(4-methoxyphenyl)-4-ethyl-4-phenyl-1,2-thiazetidin-3-one 1-oxide 
• 13463-40-6 iron pentacarbonyl 
• 14741-34-5 tricarbonyl bis(triphenylphosphine) iron 
• 35679-07-3 tetracarbonyl(triphenylphosphine)iron 
• 85134-75-4 [Fe(triphenylphosphine)2(CO)2(4-MeOC₆H₄NSO)] 
• 133213-32-8 C₁₄H₁₄N₂OS 
• 181651-35-4 N-(4-methoxyphenyl)-N-methyl-1-phenylethenesulfinamide 
• 181651-34-3 N-(4-methoxyphenyl)-N-(tert-butyldimethylsilyl)ethenesulfinamide 
• 181651-33-2 N-(4-methoxyphenyl)-N-(trimethylsilyl)ethenesulfinamide 
• 181651-32-1 N-ethyl-N-(4-methoxyphenyl)ethenesulfinamide 
• 181651-31-0 N-(4-methoxyphenyl)-N-methylethenesulfinamide 

Relevant articles and documents

Synthesis of benzo-ortho-thiazines S-oxides by diels-alder reaction of N-sulfinylanilines with norbornadiene

From substituted N-sulfinylanilines acting as dienes in the Diels-Alder reaction with norbornadiene S-oxides of benzo-ortho-thiazines were obtained, which were oxidized into the corresponding S,S-dioxides belonging to the class of hybrid thiazinesulfonami

Substituted N-aryl alk-1-enesulfinamides: Preparation, properties and conversion into the corresponding indole compounds [1]

Reaction of vinylic organometallic derivatives with N-sulfinyl arenamines 2 affords the title sulfinamides 3. On heating their solutions in selected solvents to 80-124 °C, these sulfinamides are converted into the corresponding indoles 6, probably via a [3.3]-sigmatropic rearrangement to intermediates VIII which undergo an intramolecular carbophilic reaction of the nitrogen atom with the neighboring sulfine group, followed by elimination of HSOH. The triethyloxonium tetrafluoroborate- or boron trifluoride etherate catalyzed conversion 3 → 6 can be carried out at a much lower temperature. Elsevier,.

NEW FACILE SYNTHESIS OF N-SULFINYLAMINE DERIVATIVES USING N,N'-SULFINYLBISIMIDAZOLE AND N-(CHLOROSULFINYL)IMIDAZOLE

Treatment of amine derivatives such as amines, sulfonamides, and amides with N,N'-sulfinylbisimidazole (1) and N-(chlorosulfinyl)imidazole (2) in situ respectively gives the corresponding N-sulfinylamine derivatives (3): the latter reaction using N-(chlor